Elfis Elmas put Napoli ahead on four minutes.
Osimhen conjured a sublime dink over the goalkeeper to double Napoli’s lead four minutes later.
Kosta Manolas then nodded home Matteo Politano’s corner in the 15th minute.
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Osimhen then scored Napoli’s fourth and his second of the game with a shot from the edge of the box in the 20th minute.
The Nigeria international rounded the goalkeeper and tapped the ball into an empty net to make 5-0 in the 35th minute.
He scored his fourth of the game four minutes later.
The 22-year-old was replaced at half-time.
Napoli will intensify their preparations for the 2021-22 Serie A campaign with fixtures against Serie C club Pro Vercelli and Bundesliga champions Bayern Munich on July 24 and 31 respectively.
The Parthenopeans will begin their new season with a date against Venezia at the Stadio Diego Armando Maradona on August 21.
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